Bimetallic metal-organic framework-derived porous one-dimensional carbon materials for electrochemical sensing of dopamine

In this work, we report the preparation of one-dimensional (1D) bimetallic zinc-cobalt BTC (BTC = 1,3,5-benzenetricarboxylate) metal–organic frameworks (MOFs) with varying Zn/Co ratios and their conversion to hierarchical porous Co/C hybrids with a trace amount of Zn (5 nm)), and high surface area, leading to improved ion/electron transfer (based on the EIS analysis), and more electrochemically active sites (confirmed by ECSA measurements) to promote a greater oxidation of DA molecules. The anti-interference test of this ZC31-BTC700°C-modified GCE (ZC31-BTC700°C/GCE) indicates its high selectivity toward DA even in the presence of interferents, such as glucose, ascorbic acid, and uric acid. Moreover, the stability test indicates the good retainment of the current response of ZC31-BTC700°C/GCE toward DA over a period of 2 weeks.