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Abstract Four donor‐acceptor boron difluoride complexes based on the carbazole electron donor and the 1,3,5,2oxadiazaborinino3,4‐ a 1,8naphthyridine acceptor were designed, synthesized, and systematically spectroscopically investigated in solutions, in dye‐doped polymer films, and in the solid states. The dyes exhibit an intense blue to red solid‐state emission with photoluminescence quantum yields of up to 59 % in pure dye samples and 86 % in poly(methyl methacrylate) films. All boron complexes show aggregation‐induced emission and reversible mechanofluorochromism. The optical properties of these dyes and their solid state luminescence can be tuned by substitution pattern, i. e., the substituents at the naphthyridine unit. Exchange of CH 3 ‐ for CF 3 ‐groups does not only increase the intramolecular charge transfer character, but also provides a crystallization‐induced emission enhancement.
Potopnyk et al. (Fri,) studied this question.