Combining Solid Solution Strengthening and Second Phase Strengthening for Thinning Li Metal Foils

Thin lithium (Li) metal foils have been proved to be indispensable yet elusive for practical high-energy-density lithium batteries. Currently, the realization of such thin foils (xAg-LiF skeleton in the composite facilitates Li diffusion kinetics and uniform Li deposition, where the thin Li-AgF electrode displays a prolonged cycle life over 500 h at 1 mA cm-2 and 1 mAh cm-2 in a carbonate electrolyte. Coupled with a commercial LiCoO2 cathode (3.4 mAh cm-2), the LiCoO2||Li-AgF cell delivers a notable capacity retention of ∼90% over 100 cycles at 0.5 C with a low negative/positive ratio of 2.5.