Key points are not available for this paper at this time.
Polyurethane (PU) foams are produced from toxic, petrochemical- and phosgene-derived isocyanates. Although nonisocyanate polyurethane (NIPU) has shown promise as a replacement for traditional PU, the synthesis of NIPU foams has not been widely studied due to the difficulties in replicating the foaming process of PU, in situ CO2 production through the hydrolysis of isocyanates. Hereby, we report the synthesis of amine-CO2 adducts and their CO2 adsorption-desorption characteristics under different conditions. The results show that the amine-CO2 adducts can exhibit up to 87% CO2 desorption at 60 °C after aminolysis with cyclic carbonate. The amine-CO2 adduct is used as both a foaming agent and a comonomer to obtain low-density foams (0.203-0.239 g·cm-3) after heating at 50-60 °C for 24-48 h. This marks the successful synthesis of in situ CO2-blown NIPU foams using an amine-CO2 adduct.
Choong et al. (Wed,) studied this question.