This study investigates the synergistic effects of combining polyphosphoric acid (PPA) and styrene–butadiene–styrene (SBS) as modifiers in asphalt binders to enhance their performance. The research focuses on optimizing the concentrations of PPA and SBS to improve the resistance to permanent deformation, cracking at intermediate and low temperatures, and resistance to aging. A series of empirical and rheological tests, including penetration, softening point, elastic recovery, dynamic shear rheometer (DSR), multiple stress creep recovery (MSCR), and bending beam rheometer (BBR), were conducted to evaluate the rheological and engineering properties of the modified binders. The results indicate that PPA can partially replace SBS, offering comparable improvements in high-temperature performance and creep resistance. The MSCR test revealed a statistically significant synergistic effect between PPA and SBS, resulting in improved recovery and reduced non-recoverable compliance. However, PPA alone shows limited effectiveness at low temperatures and in properties that are governed by elastic response. This study highlights the potential for optimizing asphalt modifiers by leveraging the complementary properties of PPA and SBS in hybrid systems, particularly regarding high-temperature properties and dynamic loading.
Veselý et al. (Sun,) studied this question.