The increasing demand for platinum group metals (PGMs) and critical base metals (BMs) underscores the critical roles these metals play in renewable energy and advanced technologies, enabling more efficient, environmentally sustainable operations. A hydrometallurgical approach to Au, Pd, and Pt tailings, derived from the glycine leaching of low-grade nickel and iron sulfide flotation concentrates, is investigated. The proposed process evaluates two glycine-based systems: glycine combined with KMnO4 and catalyzed by cyanide under starvation conditions. Leaching with glycine in the presence of KMnO4 (72 h, 25% solids, 60 °C, pH 11, dissolved oxygen 10 ppm, 126.7 kg/t glycine, and 7 kg/t KMnO4) achieved extraction efficiencies of up to 66.7% Au, 89.1% Pd, and 95.8% Pt. In comparison, the cyanide-starved glycine system (72 h, 30% solids, 60 °C, pH 11, dissolved oxygen 20 ppm, 98.5 kg/t glycine, and 3.3 kg/t cyanide) resulted in up to 80.8% Au, 78.3% Pd, and 14.3% Pt. Activated carbon and Amberlite resin demonstrated selective adsorption of Au and PGMs. For activated carbon, Au adsorption exhibited a non-linear dependence on carbon dosage, reaching a maximum of 77.61% at 20 g/L, then decreasing to 50.85% at 25 g/L, and finally increasing to 65.04% at 30 g/L, indicating variable adsorption behavior. In contrast, Amberlite resin exhibited more consistent, progressive adsorption with increasing dosage. Au adsorption remained high across all conditions, increasing from 88.06% at 10 g/L to 99.67% at 30 g/L. Similarly, Pd and Pt adsorption improved significantly with resin dosage, reaching maximum values of 81.32% and 83.36% at 25 g/L, respectively, followed by a slight decline at 30 g/L. Implementing a two-stage process using carbon + resin (30 g/L) increased PGM recovery, achieving 99.89% Au, 81.8% Pd, and 92.4% Pt. Elution tests showed that Au (61.97%) and Pd (60.55%) were desorbed efficiently using thiourea (2% w/v) and HCl (0.5 M), whereas Pt elution proved difficult and required alternative strategies. The findings confirm glycine-based technologies as a promising, environmentally friendly alternative to conventional methods and provide a basis for further process development and optimization.
Solano et al. (Wed,) studied this question.