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The decarboxylation of free carboxylic acids was effected by a photogenerated cation radical of phenanthrene to yield the reduction product in the presence of a thiol, which provides an alternative method to the Barton decarboxylation procedure for aliphatic acids such as N-Boc amino acids.
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Yasuharu Yoshimi
University of Fukui
Tatsuya Itou
University of Toyama
Minoru Hatanaka
Azabu University
Chemical Communications
University of Fukui
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Yoshimi et al. (Mon,) studied this question.
synapsesocial.com/papers/6a02ade7daa0ebdf9f9e2b07 — DOI: https://doi.org/10.1039/b714526h