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A change in the spectral shape at 681 nm is used to distinguish blooms of cyanobacteria from blooms of other phytoplankton via MERIS satellite sensor imagery. During large cyanobacterial blooms, the spectral shape around 681 nm is not a positive quantity as scattering due to cyanobacteria overwhelms the fluorescence signal, thus creating a negative spectral shape. This relationship is consistent in both remotely sensed and in situ data.
Wynne et al. (Fri,) studied this question.