Evidence for freeze–thaw events and their implications for rock weathering in northern Canada: II. The temperature at which water freezes in rock

Abstract Many undertakings have used either a single value or a narrow window of temperatures as a threshold for the freezing of water within rock. These temperatures vary from 0 to −5 C, with most windows being in the range −1 to −4 C. Based on thermal data, these thresholds are commonly used to ‘count’ the number of freeze–thaw events as a basis for determining freeze–thaw weathering. Data collected from northern Canada indicate that the temperature at which freezing occurs can vary substantially, even for the same site. Using exotherm and zero curtain observations from bricks, at angles of 90 and 45, aligned to the four cardinal aspects, the various temperatures at which water froze are shown. Bricks on the north and east commonly did exhibit freezing, based on exotherms, within the window −1 to −5 C, while data for the south and west aspects showed substantial variation, with freezes sometimes between −6·4 and −8·9 C. The data were evaluated for evidence of zero curtain effects (indicative of water freezing), but no unequivocal events could be found, and it is suggested that, at the scale of observation used here, they are unlikely. It would therefore appear that the use of thermal thresholds may not be meaningful for evaluation of freeze–thaw events. The available data also indicate many instances when temperatures went substantially sub‐zero (e.g. −20 C) and yet no indication of water freezing occurred – most likely because there was no water available to freeze. This indicates that any form of freeze–thaw event counting, in the absence of some indicator of the presence of water and that it actually froze, is flawed, as thermal conditions alone are not adequate to indicate the occurrence or not of actual freeze–thaw weathering events. These data suggest that evaluations of freeze–thaw occurrence based simply on thermal thresholds may be substantially in error. Copyright © 2006 John Wiley & Sons, Ltd.