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October 5, 2016Journal of the American Chemical Society256 citations

Deciphering the Spatial Arrangement of Metals and Correlation to Reactivity in Multivariate Metal–Organic Frameworks

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QLQi LiuHCHengjiang CongHDHexiang Deng

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Abstract

O were synthesized and characterized. These multivariate MOFs (MTV-MOFs) were examined by X-ray photoelectron spectroscopy, UV-vis diffuse reflectance spectra, and for the first time, their metal spatial arrangement deciphered and were found to exist in the form of either domains or well-mixed. We find that MTV-MOFs with well-mixed metals in their SBUs, rather than the SBUs having one kind of metal but different from one SBU to another, perform better than the sum of their parts in the test reaction involving the photo-oxidation of 1,5-dihydroxynaphthalene.

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Cite This Study

Liu et al. (2016) studied this question.

synapsesocial.com/papers/6a1b35c144ce1c160396838ehttps://doi.org/10.1021/jacs.6b08724
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