Convergent paired photocatalyzed hydroarylation of β-alkenyl ketones with cyanoaromatics enabled by radical anion sorting
Key Points
To explore regioselective hydroarylation of β-alkenyl ketones using radical anion sorting.
Utilized radical anion sorting for regioselectivity.
Conducted photocatalyzed reactions involving β-alkenyl ketones and cyanoaromatics.
Synthetic pathways led to the production of β-aryl alkylketones.
Successfully achieved regioselective hydroarylation of β-alkenyl ketones.
Generated β-aryl alkylketones as end products.
Demonstrated viability of radical anion sorting in reactions.
Abstract
Radical anion sorting-enabled regioselective convergent paired photocatalyzed hydroarylation of β-alkenyl ketones with cyano(hetero)aromatics, leading to β-aryl alkylketones, is depicted.
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Convergent paired photocatalyzed hydroarylation of β-alkenyl ketones with cyanoaromatics enabled by radical anion sorting | Synapse