January 1, 2004

Structural model of the oxygen-evolving centre of photosystem II with mechanistic implications

JBJames BarberUniversity of East Anglia KFKristina N. FerreiraImperial College London KMKarim MaghlaouiFoundation for Liver Research

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Abstract

An X-ray structure of photosystem II refined to 3.5 Å resolution has revealed details of the metal cluster and protein environment of the oxygen-evolving centre and provides a framework for developing a molecular mechanism for the water splitting reaction.

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Barber et al. (Thu,) studied this question.

synapsesocial.com/papers/6a21fffce8ef4064f24ea6ea https://doi.org/https://doi.org/10.1039/b407981g

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1Bicarbonate is an essential constituent of the water-oxidizing complex of photosystem II1997 · 86 citations
2Aspartate 170 of the photosystem II reaction center polypeptide D1 is involved in the assembly of the oxygen-evolving manganese cluster1992 · 226 citations
3The two forms of the S2 state multiline signal in Photosystem II: effect of methanol and ethanol2004 · 24 citations
4Comparison of the Manganese Oxygen-Evolving Complex in Photosystem II of Spinach and Synechococcus sp. with Multinuclear Manganese Model Compounds by X-ray Absorption Spectroscopy1994 · 143 citations
5Ca<sup>2+</sup> binding to the oxygen evolving enzyme varies with the redox state of the Mn cluster1988 · 84 citations

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