Nitrogen applied in excess of plant demand in intensive agricultural systems can be lost through runoff and leaching into surface and groundwater, with potentially negative effects on water quality. Zeolites, due to their high cation exchange capacity and internal porosity, can adsorb ammonium (NH4+) and help mitigate excessive nitrate (NO3−) leaching. Owing to such properties, zeolites can play an important role in reducing the potential negative impact associated with the extensive use of nitrogen-based fertilizers. In this study, we investigated the effects of two commercial natural zeolites on selected hydraulic properties, water storage, and solute transport parameters of three sandy-loam soils with different pedological characteristics. Laboratory experiments were conducted on disturbed soil columns. The leaching of NO3− and NH4+ ions was monitored using ion-selective electrode analysis. The results indicate that zeolite application reduces the mobility of nitrate and ammonium. This effect can be attributed to changes in the original pore size distribution of the investigated soils, characterized by a reduction in macropore regions and a corresponding increase in meso- and micropore regions. In the case of ammonium, adsorption mechanisms are also involved, which further contribute to retarding its mobility. These effects were consistently observed across the investigated soils. For a given soil, the magnitude of the observed effects depended on both the type of zeolite used and the amount of zeolite mixed with the soil. Finally, ANOVA tests and multivariate analyses were applied to the full dataset to provide statistical support for the observed changes in the selected parameters.
Comegna et al. (Fri,) studied this question.