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June 1, 2004Journal of the American Chemical Society68 citations

Isotopomer Encapsulation in a Cylindrical Molecular Capsule: A Probe for Understanding Noncovalent Isotope Effects on a Molecular Level

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DRD. RechaviScripps Research InstituteASAlessandro ScarsoCa' Foscari University of VeniceJRJulius RebekShanghai University

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Abstract

Isotope effects for the encapsulation of deuterated versus nondeuterated guests are determined. This system involves the use of social isomers, and the origin of the isotope effect is localized to methyl groups interacting with aromatic rings.

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Rechavi et al. (2004) studied this question.

synapsesocial.com/papers/6a893d836099c68714333426https://doi.org/10.1021/ja048366p
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