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September 5, 2025Journal of Fluid Mechanics0 citations

Crystal growth at a liquid–liquid interface upon drop impact

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MBMarion BerryCJChristophe JosserandASAnniina Salonen

Key Points

  • Crystals appear on a mobile interface upon drop impact, indicating significant dynamism in the growth process.
  • A constant rate of crystal formation corresponds to the thermal shock experienced during drop impact on the cool liquid bath.
  • Dimensionless curves derived from the model closely align with experimental measurements of crystal number and surface area.
  • The study enhances understanding of crystallisation in challenging liquid–liquid interfaces, potentially informing future materials research.

Abstract

The crystallisation that occurs when a drop is in contact with a cold surface is a particularly challenging phenomenon to capture experimentally and describe theoretically. The situation of a liquid–liquid interface, where crystals appear on a mobile interface is scarcely studied although it provides a defect-free interface. In this paper, we quantify the dynamics of crystals appearing upon the impact of a drop on a cool liquid bath. We rationalise our observations with a model considering that crystals appear at a constant rate depending on the thermal shock on the expanding interface. This model provides dimensionless curves on the number and the surface area of crystals that we compare with our experimental measurements.

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Cite This Study

Berry et al. (2025) studied this question.

synapsesocial.com/papers/68bb4de86d6d5674bcd01861https://doi.org/10.1017/jfm.2025.10508
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