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October 3, 2025Journal of the American Ceramic Society3 citations

Effect of rare‐earth ion substitution on structural, magnetic, and magnetocaloric properties of GdCrO3 orthochromites

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KSKuldeep SinghAKAmrita KumariVPVenkata Sreenivas Puli

Key Points

  • The maximum magnetic entropy change reaches about 28.79 J/kg K for Gd0.5Dy0.5CrO3 at 7.5 K.
  • Néel transition temperatures were found to be 154 K, 149 K, and 144 K for compounds with Dy, Ho, and Er.
  • Gd0.5Dy0.5CrO3 shows magnetization reversal behavior at an applied field of 0.01 T.
  • These compounds demonstrate promising properties for magnetic refrigeration in cryogenic applications.

Abstract

Abstract A detailed investigation of the structure, cryogenic magnetic properties, and magnetocaloric performances of Gd 0.5 R 0.5 CrO 3 (R = Dy, Ho, and Er) perovskites has been presented. The phase purity of the compounds was examined by the x‐ray diffraction. The Néel transition temperature was found 154, 149, and 144 K for compounds with R = Dy, Ho, and Er, respectively. Gd 0.5 Dy 0.5 CrO 3 compound exhibits the magnetization reversal behavior at an applied magnetic field of 0.01 T. The magnetic entropy change (−Δ S ) reaches a maximum value of 28.79, 27.56, and 26.78 J/kg K at 7.5 K with a maximum magnetic field of 8 T for compounds with R = Dy, Ho, and Er, respectively. Correspondingly, the relative cooling power attains values 604.15, 605.82, and 597.73 J/kg, respectively. These findings advocate that the Gd 0.5 R 0.5 CrO 3 (R = Dy, Ho, and Er) compounds exhibit promising magnetocaloric properties for magnetic refrigeration in cryogenic temperature range.

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Cite This Study

Singh et al. (2025) studied this question.

synapsesocial.com/papers/68e03501f0e39f13e7fa39f7https://doi.org/10.1111/jace.70281
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