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The large-scale application of aqueous Al–air batteries is highly restricted by the performance of Al anodes. The severe self-corrosion and hydrogen evolution of the Al anode in a concentrated alkaline electrolyte are the main reason. Here, aimed at relieving side reactions and enhancing the utilization of metal Al, we propose a hybrid electrolyte additive of 2-mercaptobenzothiazole (MBT) and ZnO to form a protective film at the anode/electrolyte interface and to decrease the hydrogen evolution active site. The strong absorption capability of MBT on the metal surface, along with the reduced Zn-containing layer, enables a compact protective film with high hydrogen evolution potential on the Al surface. With this benefit, the hydrogen evolution reaction (HER) inhibition efficiency is up to 83.58%, endowing a superior Al–air battery with an energy density of 2376.71 Wh kgAl–1 under a current density of 25 mA cm–2. The conception of constructing a hybrid protective film on the metal surface not only favors the development of metal–air batteries but also facilitates metal corrosion protection.
Lü et al. (2024) studied this question.