Heavy metal contamination in water poses severe environmental and health challenges, creating an urgent need for sustainable remediation strategies. In this study, magnesium ferrite (MgFe2O4) nanoparticles were biosynthesized using natural plant extracts and explored as bioadsorbents for the removal of Pb2+ and Hg2+ from wastewater. The nanoparticles were thoroughly characterized by SEM, FTIR, and XRD, confirming the formation of well-defined spinel structures (∼3.77 nm) and the presence of hydroxyl and cyano groups as active adsorption sites. Batch adsorption experiments demonstrated high removal efficiencies, with maximum capacities of 94.85 mg/g for Pb2+ and 97.37 mg/g for Hg2+, best described by the Langmuir isotherm. Kinetic analysis indicated pseudo-second-order behavior, suggesting chemisorption-driven mechanisms. Complementary DFT calculations revealed strong electronic interactions between the metal ions and the MgFe2O4 surface, supporting the experimental findings. Additionally, the nanoparticles retained their adsorption performance over five reuse cycles, highlighting their stability and cost-effectiveness. These results position biosynthesized MgFe2O4 nanoparticles as promising, sustainable materials for heavy metal remediation in water treatment applications.
Kerouad et al. (2025) studied this question.