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February 2, 2026Journal of Applied Polymer Science0 citations

Fabrication and Characterization of PAN ‐Based Electrospun Nanofibers Modified With Polypyrrole and Quantum Dots for Enhanced Dielectric and Energy Storage Applications

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SKSamar A. KhattabEKE. KenawyGRGalal H. Ramzy

Key Points

  • The research aims to develop and characterize PAN-based nanofibers modified with PPy and QDs for energy storage and dielectric applications.
  • Fabrication of three composite nanofiber samples: PAN/QD, PAN/PPy, and PAN-PPy/QD.
  • Characterization of the nanofibers’ dielectric and electrical properties.
  • Morphological analysis to determine average fiber diameter.
  • Impedance and electric modulus spectroscopy to assess charge mobility.
  • S3 composite nanofiber demonstrated the highest dielectric constant and lowest dielectric loss.
  • Charge mobility improved significantly in S3 with shorter relaxation times.
  • Uniform fiber formation observed with average diameter ranging from 274–379 nm.

Abstract

ABSTRACT In this study, electrospun composite nanofibers based on polyacrylonitrile (PAN) were developed and modified with polypyrrole (PPy) and quantum dots (QDs) to investigate their suitability for energy storage and electronic applications. Three samples PAN/QD (S1), PAN/PPy (S2), and PAN‐PPy/QD (S3) were fabricated and characterized to evaluate their dielectric and electrical properties as functions of frequency and temperature. Morphological analysis confirmed uniform fiber formation with an average diameter size in the range of 274–379 nm. The dielectric measurements demonstrated that the S3 composite nanofiber exhibited the highest dielectric constant and the lowest dielectric loss across all testing conditions, particularly at elevated temperatures. Impedance and electric modulus spectroscopy revealed improved charge mobility and shorter relaxation times in S3, attributed to the synergistic effects of PPy and QD incorporation. These enhancements affirm the potential of PAN‐PPy/QD composite as a high‐performance material for use in advanced dielectric components and flexible energy storage devices.

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Cite This Study

Khattab et al. (2026) studied this question.

synapsesocial.com/papers/6980fe8ac1c9540dea810b27https://doi.org/10.1002/app.70435
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