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February 6, 2026Powders0 citationsOpen Access

Photosensitization of TiO2 with Copper for the Photodegradation of Organic Contaminants in Water

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DPDafne Rubi Porras-HerreraDRDebany Yulissa Rincón-SalazarMMMaría Teresa Maldonado-Sada

Key Points

  • Investigate the effects of copper doping on the photocatalytic activity of TiO2 in degrading organic water contaminants.
  • Synthesize undoped and Cu-doped TiO2 powders using the mechanochemical method.
  • Characterize the photocatalyst with XRD, SEM, absorbance, and chemical analysis.
  • Conduct photocatalytic tests to evaluate the degradation of organic compounds in water.
  • XRD analysis confirmed the formation of TiO2 in anatase and rutile phases.
  • SEM images indicated sphere-like shapes of Cu-doped TiO2 nanoparticles with sizes around 100 nm.
  • Cu-doped TiO2 showed significantly enhanced photocatalytic activity for degrading organic contaminants.

Abstract

Photocatalysis is a process in which a material utilizes light energy to degrade contaminants through oxidation reactions that decompose impurities upon contact with its surface. Titanium dioxide is one of the most widely used semiconductor materials due to its abundance, chemical stability, and non-toxicity. However, its relatively wide bandgap restricts its photocatalytic activity to the ultraviolet region of the solar spectrum, limiting its overall efficiency under natural sunlight. The incorporation of copper nanoparticles into the TiO2 matrix enhances light absorption by extending its activity into the visible range, thereby improving its energy conversion efficiency. In this study, undoped and Cu-doped TiO2 powders were synthesized using the mechanochemical method. The characteristics of the prepared photocatalyst material were determined by XRD, SEM, absorbance, and chemical analysis. XRD analysis showed the formation of TiO2 in its anatase and rutile phases. Sphere-like shapes with a size of 100 nm were inferred from SEM images. The photocatalytic tests revealed that the Cu-doped TiO2 nanoparticles exhibited high photocatalytic activity in degrading contaminated water. This enhancement can be attributed to the formation of oxygen vacancies, which promote the photodegradation of organic compounds.

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Cite This Study

Porras-Herrera et al. (2026) studied this question.

synapsesocial.com/papers/698585ea8f7c464f23009b1chttps://doi.org/10.3390/powders5010006
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