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February 8, 2026Chemical Science0 citationsOpen Access

Modulating Halide Leaving-Group Trends through Recognition by Bisboranes

TLTong-Tong LiuXLXiao-Wen LiYCYun‐Shu Cui

Key Points

  • The study aims to investigate how anion recognition can influence the leaving-group ability of halides in chemical reactions.
  • Used dynamic anion recognition techniques.
  • Applied the recognition in nucleophilic substitution reactions.
  • Analyzed the effects of bisboranes on leaving-group trends.
  • Demonstrated enhanced leaving-group trends through bisborane recognition.
  • Showed improved reaction efficiency in nucleophilic substitutions.
  • Exhibited modulated intrinsic leaving-group tendencies of various halides.

Abstract

Modulating the intrinsic leaving-group tendency of halides remains a long-standing challenge in synthetic chemistry. Herein, we reported dynamic anion recognition and demonstrated its application in nucleophilic substitution reactions, enabling an...

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Cite This Study

Liu et al. (2026) studied this question.

synapsesocial.com/papers/698827670fc35cd7a88462dahttps://doi.org/10.1039/d5sc10013e
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