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February 9, 2026Chemical Science0 citationsOpen Access

Direct Metathesis of Carbon-Carbon σ-bonds at a Versatile Macrocycle-supported Diiron Platform

TLTianchang LiuJGJared GonderRMRyan Murphy

Key Points

  • To explore the efficiency of carbon-carbon bond metathesis using a diiron-supported macrocycle.
  • Developed a versatile macrocycle-supported diiron platform.
  • Conducted experiments to assess the metathesis of C-C σ-bonds.
  • Measured the energy efficiency of the process.
  • Successfully achieved metathesis of C-C σ-bonds.
  • Demonstrated lower energy requirements compared to traditional methods.
  • Highlighted the atom-economical nature of the reaction.

Abstract

The metathesis of C-C σ-bonds holds potential as an atom-economical strategy for molecular engineering. While this reaction has been achieved in industrial and research settings, the former is energy-intensive and...

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Cite This Study

Liu et al. (2026) studied this question.

synapsesocial.com/papers/698979a6f0ec2af6756e77dehttps://doi.org/10.1039/d5sc10054b
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