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February 12, 2026Journal of Environmental Management3 citationsOpen Access

Impact of coupling biochar and clay minerals on physicochemical properties of sandy soils and CH4/CO2 flux for agriculture

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AAAbdelhamid AdsMMMohamed G. MoussaAEAhmed H. El-Naggar

Key Points

  • This research aims to assess how biochar and different clay minerals affect the physical and chemical properties of sandy soils and their greenhouse gas flux.
  • Evaluated zeolite, bentonite, and aluminum hydroxide at 2, 5, and 10 wt% with and without biochar.
  • Conducted experiments under greenhouse conditions to measure soil properties and gas emissions.
  • Analyzed soil bulk density, aggregation, available water content, and gas exchange for treatments.
  • All clay minerals reduced soil bulk density and improved water retention, especially with biochar.
  • 10% bentonite + biochar resulted in the highest available water content increase (+172%).
  • Al(OH)3 + biochar significantly increased CO2 emissions by +2346%; CH4 fluxes remained negative (uptake).
  • Millet showed the best growth response at 5% Al(OH)3 + biochar (+312%).

Abstract

Sandy soils present key limitations to sustainable agriculture due to low water retention, poor aggregation, and limited nutrient-holding capacity, motivating the use of amendments to overcome these constraints. This study evaluated zeolite, bentonite, and aluminum hydroxide (Al(OH)3) at 2, 5, and 10 wt%, with and without biochar, on the physical, chemical, and gas-exchange properties of a sandy soil in addition to an agronomy implication under greenhouse conditions. Results showed that all clay minerals reduced soil bulk density, improved aggregation, and increased available water content (AWC), particularly with biochar (e.g., 10% bentonite + biochar gave the highest AWC, +172%; 10% Al(OH)3 + biochar produced the lowest bulk density, -12%). Biochar's effects were not always additive, as it moderated chemical shifts by buffering pH and reducing EC. In gas exchange, Al(OH)3 markedly increased CO2 emissions (+1833%), and this effect further amplified with biochar (+2346%), while CH4 fluxes remained negative (uptake). To verify agricultural relevance, millet was cultivated under identical greenhouse conditions. In soil only treatments, all minerals exceeded the control; the best response occurred at 5% Al(OH)3 (+278%), followed by 5% bentonite (+160%). Increasing to 10% did not add benefit because EC with Al(OH)3 and wilting point with bentonite rose significantly that inversely affect the plants growth. With biochar, responses increased overall, peaking at 5% bentonite + biochar (+315%) and 5% Al(OH)3 + biochar (+312%). These results provide practical guidance for selecting amendment combinations to balance water retention, fertility, aeration, and greenhouse gas outcomes.

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Cite This Study

Ads et al. (2026) studied this question.

synapsesocial.com/papers/698d6d445be6419ac0d52293https://doi.org/10.1016/j.jenvman.2026.128881
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