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February 17, 20260 citationsOpen Access

Structural Characterization and Photocatalytic Performance of PDMS/TiO2 Nanocomposites Prepared via Ex Situ Dispersion Route

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AHAbdelkader Hassein-BeyNBNadir BelgrouneABAssia Bessi

Key Points

  • The study aims to develop PDMS/TiO2 nanocomposites to improve photocatalytic performance and mechanical properties.
  • Elaborated PDMS/TiO2 nanocomposites via an ex situ dispersion route.
  • Utilized X-ray diffraction for structural characterization.
  • Monitored photocatalytic performance using UV-visible spectroscopy with metronidazole.
  • Conducted kinetic analysis to assess degradation rates.
  • XRD confirmed successful incorporation of TiO2 into the PDMS matrix.
  • Photocatalytic degradation rates increased with higher TiO2 loading, achieving a maximum k of 0.0019 min−1 for the 6 wt.% composite.
  • PDMS/TiO2 nanocomposites offer a flexible and recoverable solution for environmental remediation, despite slower kinetics compared to free powders.

Abstract

This work reports the elaboration and testing of polydimethylsiloxane/titanium dioxide (PDMS/TiO2) polymer nanocomposites, focusing on producing and combining TiO2 nanoparticles with a polymer matrix through an ex situ route. By mixing the inherent flexibility of PDMS with the unique properties of nanoparticles, the nanocomposites aim to enhance mechanical stability, optical response, and photocatalytic activity. X-ray diffraction (XRD) confirmed the successful incorporation of TiO2 into the PDMS matrix. UV–visible spectroscopy monitored photocatalytic performance using metronidazole as a model pollutant under 365 nm irradiation. Kinetic analysis revealed degradation and showed that the reaction rate constant (k) increased with TiO2 loading, reaching a maximum of 0.0019 min−1 for the 6 wt.% composite. These findings indicate that while the reaction kinetics are slower than those of free powders, the PDMS/TiO2 nanocomposites provide a viable, recoverable, and flexible solution for environmental remediation applications. Future efforts will target improved durability, broadened visible light absorption, and process optimization for scalable fabrication.

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Cite This Study

Hassein-Bey et al. (2026) studied this question.

synapsesocial.com/papers/699405494e9c9e835dfd619ehttps://doi.org/10.3390/applmech7010018
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