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February 19, 2026Dalton Transactions2 citations

Monocoordinated nitrenes and heavier pnictinidenes: transient to bottleable compounds

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SKS. Sunil KumarKTK. B. TomerASAvnish Singh

Key Points

  • The aim is to explore the recent developments in synthesizing stable nitrenes and pnictinidenes.
  • Reviewed recent synthetic methods for isolating nitrenes and pnictinidenes
  • Analyzed bonding characteristics in the condensed phase
  • Compiled examples of stability under ambient conditions
  • Nitrenes and pnictinidenes are now isolable and stable
  • Unusual bonding patterns observed in condensed states
  • Significant advances in synthetic techniques reported

Abstract

Nitrenes and heavier pnictinidenes, once viewed as transient intermediates, are now isolable and stable under ambient conditions. This perspective briefly reviews their recent synthetic advances and unusual bonding in the condensed phase.

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Cite This Study

Kumar et al. (2026) studied this question.

synapsesocial.com/papers/6996a8c7ecb39a600b3efe31https://doi.org/10.1039/d5dt02995c
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