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February 20, 2026Chemical Communications0 citationsOpen Access

„Inverted” hysteresis in bilayer Fe(II) spin crossover system

ATAleksandra TołoczkoMKMarcin KaźmierczakVMVladyslav Maliuzhenko

Key Points

  • To investigate the unique thermal hysteresis properties in a bilayer Fe(II) spin crossover system.
  • Analyzed the coupling between spin states and alkyl chain dynamics.
  • Characterized thermal hysteresis in the context of spin transitions.
  • Conducted experiments to observe the behavior of high-spin to low-spin states.
  • Observed an inverted hysteresis loop during the high-spin to low-spin transition.
  • Demonstrated that individual alkyl chain motions significantly influence spin state behavior.
  • Highlighted the unique coupling mechanism contributing to the observed hysteresis.

Abstract

The coupling between the spin state and the complex motion of the individual alkyl chains results in a unique thermal hysteresis exhibiting an "inverted” loop. Specifically, the high-spin (HS) ...

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Cite This Study

Tołoczko et al. (2026) studied this question.

synapsesocial.com/papers/6997fa12ad1d9b11b3452fddhttps://doi.org/10.1039/d6cc00357e
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