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February 21, 2026Chemical Communications0 citations

Hydride-Mediated Ammonia Borane Dehydrogenation in Water by Arene-Ru(II) Catalysts Revealed through Real-Time Gas Evolution

TNThillai M. NatarajanSPSumanta Kumar Padhi

Key Points

  • To examine the efficiency of arene-Ru(II) complexes as catalysts in ammonia borane dehydrogenation in water.
  • Kinetic analysis of the dehydrogenation reaction
  • Investigation of the effect of catalyst concentration
  • Measurement of gas evolution in real-time
  • Achieved high turnover number (TON) and turnover frequency (TOF) for ammonia borane dehydrogenation
  • Demonstrated pseudo-first-order kinetics concerning both Ru catalyst and ammonia borane
  • Confirmed effective catalytic performance at room temperature (25 °C)

Abstract

Arene-Ru(II) complexes catalyse efficient Ammonia Borane (AB) dehydrogenation in water at 25 °C, delivering high TON and TOF. Kinetic analysis reveals pseudo-first-order behaviour on both Ru and AB; a hydride-Ru...

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Cite This Study

Natarajan et al. (2026) studied this question.

synapsesocial.com/papers/69994bef873532290d0200c8https://doi.org/10.1039/d5cc06735a
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