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February 22, 2026Glass Physics and Chemistry0 citations

Size Dependence of the Density of Certain Substances

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MAM. Yu. Arsent’evMSM. M. Sychev

Key Points

  • The research aims to explore how the density of nanoparticles changes with their size and the factors influencing this relationship.
  • Proposed methods for assessing changes in nanoparticle density based on particle size.
  • Calculated density values for nanoparticles of C, Fe, Si, and ZrO2.
  • Examined density oscillations in relation to the number of atoms in nanoparticles.
  • Density oscillations in nanoparticles correlate with their radius.
  • Oscillations disappear when particles contain around 10,000 atoms.
  • Density values for larger particles approach those of bulk materials.

Abstract

Factors influencing the density of nanoparticles include the intrinsic density of the element or compound that forms the nanoparticle, surface properties, pore structure, and agglomeration within suspensions or aggregates. In this case, the first factor is the main one; therefore, the methods for quickly assessing changes in nanoparticle density as a function of particle size, which we considered in this paper, are relevant. An estimate of the actual density of a substance is proposed depending on the number of atoms in a particle (nanoparticle). It is found that density oscillations are observed in the dependence of the nanoparticle density on its radius. Calculations are carried out for C (diamond, graphite, graphene), Fe, Si, and ZrO2. When density is considered as a function of the number of atoms, oscillations are observed, which vanish at a content of 104 atoms, after which the density approaches values similar to those of bulk materials. The values of the radius of metal microparticles correspond to the values obtained earlier by other authors when explaining the deviation of the specific heat capacity of nanoparticles from the macroscopic heat capacity, based on solutions of the Schrödinger equation. The threshold values of mass and radius are unique for each substance and are significantly smaller than the Planck mass.

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Cite This Study

Arsent’ev et al. (2025) studied this question.

synapsesocial.com/papers/699a9d3c482488d673cd309chttps://doi.org/10.1134/s1087659625600772
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