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February 28, 2026Chemical Communications0 citations

Unusual Capacity Boost in Li/TiF 3 Cells Enabled by a Li + /Na + Mixed Solid Electrolyte with High-Voltage Stability

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KSKaisei SanoRMReona MiyazakiTHTakehiko Hihara

Key Points

  • The research investigates the enhanced capacity of Li/TiF₃ cells when using a Li⁺/Na⁺ mixed solid electrolyte.
  • Utilized a Li⁺/Na⁺ mixed NaI–NaBH₄–LiI electrolyte
  • Examined interfacial Li⁺ storage mechanisms
  • Assessed high-voltage stability
  • TiF₃ displayed an unusually large capacity during tests
  • No Ti³⁺ redox activity was observed, indicating different storage mechanisms
  • Dominant process identified as interfacial Li⁺ storage

Abstract

TiF₃ exhibits an anomalously large capacity when paired with a Li⁺/Na⁺ mixed NaI–NaBH₄–LiI electrolyte. TiF 3 shows no Ti³⁺ redox during operation, indicating interfacial Li⁺ storage as the dominant process. The...

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Cite This Study

Sano et al. (2026) studied this question.

synapsesocial.com/papers/69a2877b0a974eb0d3c032c9https://doi.org/10.1039/d6cc00375c
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