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March 3, 2026Atmospheric chemistry and physics0 citationsOpen Access

Emerging Mineral Dust Source in ’A’ay Chù’ Valley, Yukon, Canada Poses Potential Health Risk via Exposure to Metal and Metalloids Enriched in PM 10 and PM 2.5 Size Fractions

ADArnold R. DowneyADAlisée DourlentDBDaniel Bellamy

Key Points

  • Exposure to mineral dust in the 'A’ą̈y Chù’ Valley has exceeded 24-hour ambient air quality criteria.
  • The average airborne dust volume diameter was measured at 4.43 µm—and high levels of metal(loid)s were identified.
  • Field campaign data indicate significant enrichment of toxic metal(loid)s within PM10 and PM2.5 fractions relative to total soil.
  • These findings highlight an emerging environmental change with potential implications for human health and local policies.

Abstract

Abstract. The ’A’ą̈y Chù’ Valley in Kluane National Park and Reserve, Yukon, Canada has undergone significant hydrological change in the past decade due to climate-driven glacial recession. This has reverted the ’A’ą̈y Chù’ to a major source of sediment-derived mineral dust, representing an environmental change for the region. Mineral dust influences climatic radiative forcing and impacts human health, both of which depend on its concentration, size distribution, and composition. This work discusses results from a field campaign conducted in the ’A’ą̈y Chù’ Valley in 2021 aimed at understanding and quantifying these parameters, with comparison to a previous campaign in the same location to evaluate the evolution of the dust emissions between 2018 and 2021. An optical particle counter (OPC) instrument measured a mean volume diameter of airborne dust of 4.43 µm at 3.3 m above ground, with Coulter Counter measurements being used for comparison and validation. The concentration of many metal(loid)s in the dust were also studied: Al, Ag, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Ni, Pb, Rb, Tl, U, and V. It was found that 24 h ambient air quality criteria for exposure to several metal(loid)s were surpassed. Significant enrichment of several metal(loid)s was observed for both the PM10 and PM2.5 size fractions relative to the Total Suspended Material (TSP) fraction of the mineral dust and the parent soil. This suggests that the mineral dust in the ’A’ą̈y Chù’ Valley possesses compounding characteristics that are detrimental to human health due to exposure to potentially toxic metal(loid) concentrations.

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Cite This Study

Downey et al. (2026) studied this question.

synapsesocial.com/papers/69a75b57c6e9836116a22823https://doi.org/10.5194/acp-26-1321-2026
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