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March 12, 2026Minerals0 citationsOpen Access

Petrogenesis of Epimetamorphic Rock from an Ion-Adsorption-Type REE Deposit in Ningdu County, Southern Jiangxi, China: Contraints from U–Pb Geochronology and the Geochemistry of Zircon and Apatite

WWWei WanHFHuihu FanDWDan Wu

Key Points

  • This research aims to investigate the petrogenesis and age of epimetamorphic rocks associated with ion-adsorption-type REE deposits.
  • Conducted petrographic analysis of epimetamorphic rocks.
  • Performed LA-ICP-MS U–Pb dating on zircon and apatite.
  • Analyzed trace elements in zircon and apatite.
  • Estimated magmatic crystallization temperatures using zircon Ti thermometry.
  • Found that the protolith of the metamorphic tuff formed around 700 Ma, indicating mid-Neoproterozoic magmatic activity.
  • Determined that the crystallization temperature of the magmatic source ranged from 623 to 723 °C.
  • Revealed that the rock formed in a back-arc extension or intra-arc rifting tectonic setting.
  • Identified extensive fractional crystallization during magmatic evolution, enriching REE potential.

Abstract

In recent years, an ion-adsorption type REE deposit has been discovered for the first time in the weathering crust of epimetamorphic rocks in Ningdu County, Jiangxi Province, which provides a new idea for the exploration of ion-adsorption-type REE deposits. However, most previous studies on the ore-forming parent rocks of ion-adsorption-type REE deposits have focused on granites and volcanic rocks, while studies on epimetamorphic rocks remain extremely scarce. In this paper, petrographic analysis of epimetamorphic rocks, LA-ICP-MS U–Pb dating and trace element analysis of zircon and apatite were conducted on the metamorphic tuff from the Kuli Formation in Ningdu County, Jiangxi Province, so as to constrain the formation age and tectonic dynamic setting of the rock mass, investigate the petrogenesis and material source of the rock mass, and reveal the metallogenic potential of the rock mass. The results of zircon and apatite U–Pb dating show that the protolith of the metamorphic tuff from the Kuli Formation formed at ca. 700 Ma, representing a product of mid-Neoproterozoic magmatic activity. The protolith restoration of metamorphic rocks suggests that the protolith of the metamorphic tuff from the Kuli Formation is magmatic rock. The estimated results of zircon Ti thermometry indicate that the magmatic crystallization temperature ranges from 623 to 723 °C, with an average value of approximately 696 °C, and the calculated zircon oxygen fugacity values vary from −18.7 to −9.4, with an average of −13.8, implying that the rock formed under conditions of relatively low temperature and high oxygen fugacity. The correlation diagrams of trace elements and element ratios in zircon and apatite reveal that the magmatic evolution involved extensive fractional crystallization of minerals such as zircon, monazite, apatite, titanite, rutile, and plagioclase during the formation of the rock mass. The discrimination diagrams of trace elements in zircon and apatite demonstrate that the metamorphic tuff from the Kuli Formation was formed in a continental margin arc or arc-related orogenic belt, and the magmatic source is characterized by crust–mantle mixing. Combined with previous research findings on regional tectonic-magmatic activities, it can be concluded that the metamorphic tuff from the Kuli Formation was formed in a tectonic setting of back-arc extension and intra-arc rifting caused by the rollback of the subducting oceanic slab. The upwelling of the asthenospheric mantle induced the partial melting of arc-derived sediments in the continental crust, which was subsequently mixed with mantle-derived magma, ultimately generating the parent magma of the metamorphic tuff. The metamorphic tuff from the Kuli Formation in Ningdu County, Jiangxi Province, has high REE abundance and relatively easily weathered REE mineral assemblages, which can provide sufficient material sources for ion-adsorption REE mineralization and have a great metallogenic potential for ion-adsorption REE deposits.

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Cite This Study

Wan et al. (2026) studied this question.

synapsesocial.com/papers/69b2588496eeacc4fcec8337https://doi.org/10.3390/min16030283
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