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March 12, 2026Geophysical Research Letters3 citationsOpen Access

Two‐Stage Dolomite Formation in Carbonate Platforms Revealed by Carbonate Clumped Isotope Thermometry

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YLYaël LevensonJEJ. M. EilerEWEyal Wurgaft

Key Points

  • This research investigates the formation processes of dolomite in Cenozoic marine environments and the contributing factors for its scarcity.
  • Measured carbon, oxygen, and clumped isotope compositions of carbonate rocks from the Nahal Me'arot reef complex.
  • Analyzed the relationships between temperatures and oxygen isotopes in dolomite samples.
  • Compiled Mg/Ca ratios in Cenozoic marine carbonates to compare predicted versus observed dolomite abundance.
  • Identified a negative trend between clumped isotope temperatures and δ 18 O values in dolomite.
  • Supported a two-stage dolomite formation process, including proto-dolomite formation and recrystallization during burial.
  • Demonstrated that thermal maturity limitations contributed to reduced dolomite formation in Cenozoic strata.

Abstract

Abstract The “dolomite problem” refers to the scarcity of dolomite in Cenozoic marine environments compared with its abundance in earlier strata. This discrepancy has been attributed to changes in marine environments or to insufficient thermal maturity required for dolomite formation. We measured carbon, oxygen, and clumped isotope compositions of carbonate rocks from the Albian Nahal Me'arot reef complex (north Israel), where dolomite is confined to back‐reef lagoon facies and associated with reflux‐brine dolomitization, a process thought responsible for large volumes of dolomite in Phanerozoic rocks. Results show a negative trend between TΔ 47 (29–54°C) and δ 18 O dolomite (−3.25 to −1.35 ‰VPDB), consistent with burial alteration, and support a two‐stage process: (a) proto‐dolomite formation near the lagoon floor, and (b) recrystallization during burial. Together with compilations of Mg/Ca ratios in Cenozoic marine carbonates predicting more dolomite than observed directly, our results suggest that insufficient thermal maturity has limited dolomite formation in Cenozoic strata.

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Cite This Study

Levenson et al. (2026) studied this question.

synapsesocial.com/papers/69b2588496eeacc4fcec84e1https://doi.org/10.1029/2025gl120386
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