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March 13, 2026CivilEng0 citationsOpen Access

Optimization of Compressive Strength and Drying Shrinkage of Calcium-Based Alkali-Activated Mortars Using Expansive and Shrinkage-Reducing Agents

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SNSeunghyun NaWZWenyang ZhangWLWoonggeol Lee

Key Points

  • This research aims to determine the optimal content levels of calcium hydroxide, expansive agents, and shrinkage-reducing agents to enhance the performance of alkali-activated mortars.
  • Conducted experiments on 17 mortar mixtures containing calcium hydroxide, calcium sulfoaluminate, and shrinkage-reducing agents.
  • Analyzed compressive strength and length change across different fixed substitution ratios of agents.
  • Performed microstructural analysis using pH measurements, porosity analysis, and X-ray diffraction.
  • Optimal contents for agents were found to be 8.54 wt.% for calcium hydroxide, 10.0 wt.% for expansive agent, and 0.76 wt.% for shrinkage-reducing agent.
  • CSA significantly increased compressive strength and dimensional stability of the mortar through a reduction in porosity.
  • SRA improved dimensional stability but slightly reduced compressive strength.

Abstract

Alkali-activated materials can significantly reduce carbon dioxide emissions compared with cement. However, their durability remains insufficiently understood. This study investigated the effects of calcium hydroxide (Ca(OH)2, CH), an expansion agent (calcium sulfoaluminate, CSA), and a shrinkage-reducing agent (SRA) on the compressive strength and length change and determined the optimal content levels for each agent. Experiments were conducted to evaluate the compressive strength and length change of 17 mortar mixtures containing CH, CSA, and SRA. The substitution ratios of CH, CSA, and SRA were fixed at three predefined levels for each factor. The microstructural changes induced by the use of each agent were analyzed using pH measurements, porosity analysis, and X-ray diffraction. In addition, the water desorption behaviors associated with CSA and SRA were assessed. Experimental and statistical analyses demonstrated that the optimal contents of CH, CSA, and SRA for simultaneously improving the compressive strength and length change were 8.54, 10.0, and 0.76 wt.%, respectively. The use of CSA significantly enhanced the compressive strength development and dimensional stability of the mortar. This improvement was associated with a reduction in the porosity, which was attributed to ettringite formation. Furthermore, while the SRA slightly reduced the compressive strength, it significantly improved the dimensional stability.

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Cite This Study

Na et al. (2026) studied this question.

synapsesocial.com/papers/69b3ac0a02a1e69014ccd6c9https://doi.org/10.3390/civileng7010016
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