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March 21, 2026International Journal of Modern Physics B0 citations

Characteristic NIR luminescence in Nd 3+ doped BiMg 2 VO 6 double metal vanadate

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SKSupriya KshetrapalNUN. S. UgemugeHAH. S. Ahamad

Key Points

  • This research aims to explore NIR emission properties in Nd3+ doped BiMg2VO6 for various applications.
  • Synthesis of pristine and Nd3+ doped BiMg2VO6 powders using solid state reaction method.
  • Characterization of materials to analyze PL emission spectra.
  • Investigation of the effect of Nd3+ concentration on luminescence intensity.
  • NIR emission was detected in BiMg2VO6 with a peak at 1070 nm.
  • Maximum luminescence intensity was found for a Bi0.095Nd0.05Mg2VO6 composition.
  • No decrease in luminescence intensity observed with higher Nd3+ concentrations.
  • Nd3+ ions were found to exchange energy within 17.13 Å proximity.

Abstract

Near infrared (NIR) emission is important for several applications. Search for new hosts suitable for NIR emission continues to be a topic of interest for researchers. In this article we describe NIR emission in BiMg 2 VO 6 . Nd 3+ was used as an activator for obtaining NIR emission. Pristine and doped BiMg 2 VO 6 powders were synthesized by using solid state reaction method. BiMg 2 VO 6 crystallizes in the Pmcn space group. In the PL emission spectra, characteristic lines, with the most intense appearing at 1070 nm, were observed. The excitation also is through transitions within Nd 3+ f shell. Results on the effect of activator concentration on the luminescence intensity are also reported. The maximum intensity is observed for the composition Bi 0.095 Nd 0.05 Mg 2 VO 6 . No decrease was observed for higher concentration. Taking concentration dependence as the basis, the calculations were made which show that Nd3+ ions exchange energy among themselves when they come closer than 17.13 Å.

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Cite This Study

Kshetrapal et al. (2026) studied this question.

synapsesocial.com/papers/69be38216e48c4981c6784dfhttps://doi.org/10.1142/s0217979226501274
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