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March 25, 2026Geostandards and Geoanalytical Research1 citations

Kovdor‐ GRT – A New Natural Reference Material for Garnet U‐Pb Dating

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MSMaria StifeevaESEkaterina SalnikovaEAE. V. Adamskaya

Key Points

  • The aim is to evaluate Kovdor-GRT garnet as a potential reference material for U-Pb geochronology.
  • Characterized major and trace element compositions of Kovdor garnet.
  • Conducted U-Pb age determinations using ID-TIMS and LA-ICP-MS methods.
  • Analyzed isotopic ratios of 206Pb/238U, 207Pb/235U, and 207Pb/206Pb.
  • Employed statistical evaluations like MSWD to assess data consistency.
  • Determined a weighted mean 206Pb/238U age of 376.50 ± 0.9 Ma.
  • Found isotopic ratios consistent across ID-TIMS and LA-ICP-MS measurements.
  • Demonstrated low common Pb content enhances age determination accuracy.

Abstract

Calcic garnet is a common component of skarns, alkaline igneous rocks and carbonatites. Recent studies report garnet laser ablation‐ICP‐MS U‐Pb ages ranging from ca . 20 to 3100 Ma demonstrating the advantages of garnet for U‐Pb geochronological studies. However, calibration using well‐characterised matrix‐matched reference materials is a critical issue for accurate age determinations. In this study we present the major and trace element compositions, and U‐Pb systematics obtained from isotope dilution‐TIMS and LA‐ICP‐MS measurements for Kovdor (Kovdor‐GRT) andradite‐shorlomite‐morimotite garnet (Kola Alkaline Province, Kola Peninsula) as a potential reference material for LA‐ICP‐MS U‐Pb dating. ID‐TIMS gave 206 Pb/ 238 U, 207 Pb/ 235 U and 207 Pb/ 206 Pb Pb c ‐corrected weighted mean ratios of 0.06008 ± 0.00018 (2 s , MSWD = 4.5), 0.4495 ± 0.0013 (2 s , MSWD = 1.6) and 0.0542 ± 0.0006 (2 s , MSWD = 0.001), respectively. The weighted mean 206 Pb/ 238 U age is 376.50 ± 0.9 Ma (MSWD = 1.3), the 207 Pb/ 235 U age is 376.5 ± 0.62 Ma (MSWD = 0.83) and the 207 Pb/ 206 Pb age is 380.6 ± 1.7 (MSWD = 0.27). The Concordia age of 376.6 ± 0.86 Ma (MSWD = 0.79) for Kovdor‐GRT, determined by ID‐TIMS, is interpreted as the best estimate for its crystallisation age. The low common Pb (Pb c ) content (Pb c /Pb t varies from 0.05 to 0.08), moderate U mass fraction (12.4–33.0 μg g ‐1 ) and isotopically homogeneous composition allowed meaningful 206 Pb/ 238 U age determinations using various LA‐ICP‐MS systems. LA‐ICP‐MS measurement results are characterised by precisions fit for purpose and yield consistent 206 Pb/ 238 U ages indistinguishable from those obtained by ID‐TIMS. The results highlight the potential of Kovdor garnet as a reference material for in situ U‐Pb dating.

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Cite This Study

Stifeeva et al. (2026) studied this question.

synapsesocial.com/papers/69c37be2b34aaaeb1a67eacfhttps://doi.org/10.1111/ggr.70040
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