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April 1, 2026Polymer Chemistry0 citations

Stereochemically Purified trans-Dihydroxy-Substituted Cage Silsesquioxane-Based Bisurea Supramolecular Polymer Materials Enable Metastable-to-Thermodynamic Phase Evolution and Enhanced Modulus

KNKensuke NAKAJTJunji TakeuchiTITakahiro Iwamoto

Key Points

  • The aim is to investigate the thermal behavior and phase evolution in silsesquioxane-based polymers.
  • Stereochemical purification of trans-dihydroxy-substituted cage silsesquioxane.
  • Characterization of thermal behavior associated with phase transitions.
  • Comparison with properties of conventional covalent polymers.
  • Enhanced modulus observed during phase transitions.
  • Identification of metastable and thermodynamic states.
  • Distinctive thermal properties compared to traditional polymers.

Abstract

The dynamic nature of interactions in supramolecular polymers imparts distinctive properties compared to those of conventional covalent polymers. A deeper understanding of the thermal behavior associated with phase transitions in...

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Cite This Study

NAKA et al. (2026) studied this question.

synapsesocial.com/papers/69cd7b475652765b073a9255https://doi.org/10.1039/d6py00164e
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