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April 3, 2026Low Temperature Physics0 citations

Linking the thermal-conductivity plateau to the Cp / T 3 hump in amorphous and complex disordered solids

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YHYu. V. HorbatenkoOKO. A. KorolyukAKA. I. Krivchikov

Key Points

  • The research aims to analyze the connection between thermal conductivity plateaus and heat capacity anomalies in disordered solids.
  • Investigated a range of disordered solids including polymers and glasses.
  • Separated contributions from particle-like propagation and wave-like coherence.
  • Analyzed experimental data to extract characteristic temperatures related to transport types.
  • The temperature of the Cp/T3 hump correlates with the thermal conductivity plateau onset.
  • Demonstrated a crossover between particle-like and coherence-dominated transport.
  • Revealed universal behavior in the particle-like contribution across various systems.

Abstract

We investigate the relationship between the low-temperature thermal conductivity plateau and the hump in reduced heat capacity (Cp/T3) in a range of disordered solids, including polymers, glasses, and complex crystalline materials. Using a unified framework that separates particle-like propagation (Peierls term) and wave-like coherence contributions, we analyze experimental data to extract characteristic temperatures associated with each contribution. Our results demonstrate that the temperature of the Cp/T3 hump Tmax correlates systematically with the onset of the thermal-conductivity plateau and the crossover between particle-like and coherence-dominated transport. Normalized scaling of the particle-like contribution reveals a universal behavior across chemically and structurally diverse systems. These findings provide clear evidence of a direct link between the thermal-conductivity plateau and low-temperature heat capacity anomalies, establishing Tmax it as a robust characteristic parameter for predicting thermal transport in disordered solids.

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Cite This Study

Horbatenko et al. (2026) studied this question.

synapsesocial.com/papers/69cf5e5f5a333a821460ca34https://doi.org/10.1063/10.0043121
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