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October 1, 1934Physical Review14,633 citations

Note on an Approximation Treatment for Many-Electron Systems

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CMCHR. KN. MØLLERMPM. S. Plesset

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Abstract

A perturbation theory is developed for treating a system of n electrons in which the Hartree-Fock solution appears as the zero-order approximation. It is shown by this development that the first order correction for the energy and the charge density of the system is zero. The expression for the second-order correction for the energy greatly simplifies because of the special property of the zero-order solution. It is pointed out that the development of the higher approximation involves only calculations based on a definite one-body problem.

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Cite This Study

MØLLER et al. (1934) studied this question.

synapsesocial.com/papers/69d6c16ffca0359822aa840fhttps://doi.org/10.1103/physrev.46.618
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