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March 1, 1973Applied Optics4,489 citations

Optical Constants of Water in the 200-nm to 200-μm Wavelength Region

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GHGeorge M. HaleMQMarvin R. Querry

Key Points

  • The aim is to determine the optical constants of water across a broad wavelength spectrum.
  • Extinction coefficients k(lambda) were calculated for water at 25 degrees C by smoothing spectral data.
  • Absorption bands were postulated for missing data in the vacuum ultraviolet to soft x-ray regions.
  • A Kramers-Kronig analysis was performed to derive the index of refraction n(lambda) from the smoothed extinction coefficients.
  • Extinction coefficients were successfully obtained and smoothed across the wavelengths from 200 nm to 200 μm.
  • Postulated absorption bands provided insights into the optical behavior of water where direct data were lacking.
  • The Kramers-Kronig analysis yielded a comprehensive index of refraction for the specified wavelength range.

Abstract

Extinction coefficients k(lambda) for water at 25 degrees C were determined through a broad spectral region by manually smoothing a point by point graph of k(lambda) vs wavelength lambda that was plotted for data obtained from a review of the scientific literature on the optical constants of water. Absorption bands representing k(lambda) were postulated where data were not available in the vacuum uv and soft x-ray regions. A subtractive Kramers-Kronig analysis of the combined postulated and smoothed portions of the k(lambda) spectrum provided the index of refraction n(lambda) for the spectral region 200 nm </= lambda </= 200 microm.

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Cite This Study

Hale et al. (1973) studied this question.

synapsesocial.com/papers/69d72942cd480cb7e5f50dc6https://doi.org/10.1364/ao.12.000555
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