PulseExploreJournal ClubDebatesTrendingResearchersJournals
Instagram
HomeExploreJournal ClubTrending
Synapse
⌘+K
Synapse
February 10, 2000Analytical Chemistry976 citations

Electrostatic Axially Harmonic Orbital Trapping:  A High-Performance Technique of Mass Analysis

View Full Paper
AMAlexander Makarov

Key Points

  • This work aims to introduce a new mass analyzer technique that leverages electrostatic fields for mass analysis.
  • Developed a mass analyzer using a combination of quadrupole and logarithmic potentials.
  • Achieved ion stability through orbiting ions around an axial electrode with harmonic oscillations.
  • Utilized image current detection for transforming oscillations into mass spectra via fast Fourier transform.
  • Demonstrated high mass resolution of up to 150,000 for ions from laser ablation processes.
  • Achieved high-energy acceptance and wide mass range in mass analysis.

Abstract

This work describes a new type of mass analyzer which employs trapping in an electrostatic field. The potential distribution of the field can be represented as a combination of quadrupole and logarithmic potentials. In the absence of any magnetic or rf fields, ion stability is achieved only due to ions orbiting around an axial electrode. Orbiting ions also perform harmonic oscillations along the electrode with frequency proportional to (m/z)-1/2. These oscillations are detected using image current detection and are transformed into mass spectra using fast FT, similarly to FTICR. Practical aspects of the trap design are presented. High-mass resolution up to 150,000 for ions produced by laser ablation has been demonstrated, along with high-energy acceptance and wide mass range.

Ask AI
Helpful
Bookmark
Share
View Full Paper

Cite This Study

Alexander Makarov (2000) studied this question.

synapsesocial.com/papers/69d7298e3f906f6a06bef810https://doi.org/10.1021/ac991131p
Ask AI
Helpful
Bookmark
Share
View Full Paper