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December 24, 2017SHILAP Revista de lepidopterología24 citationsOpen Access

Thermal, photo-oxidation and antimicrobial studies of linalyl acetate as a major ingredient of lavender essential oil

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SKSuzan A. Khayyat

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Abstract

Lavender oil, obtained from the flowers of Lavandula angustifolia (Family: Lamiaceae) by steam distillation, The major component of lavender oil is linalyl acetate was isolated and subjected to oxidation thermally and photochemically using (mcpba and H2O2) respectively to produce mixture of 6,7-epoxy-3,7-dimethyl-1-octene-3-yl acetate (3) and 1,2-epoxy-3,7-dimethyl-6-octene-3-yl acetate (4) photochemically, while produced epoxide 4 only thermally. On the other hand, photooxygenation of 1 using different singlet oxygen sensitizers gave two hydroperoxide derivatives of 6-hydroperoxy-3,7-dimethylocta-1,7-diene-3-yl acetate (5) and 7-hydroperoxy-3,7-dimethylocta-1,5-diene-3-yl acetate (6) in the presence of tetraphenyl porphin (TPP), whereas gave hydroperoxide 6 only using hematoporphyrin (HP). Studies on the antimicrobial especially Microsporum canis and Microsprum gallinna showed that linalyl acetate and its epoxide and hydroperoxide derivatives have a good antibacterial action.

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Suzan A. Khayyat (2017) studied this question.

synapsesocial.com/papers/69d7adccdcc7b92a43f30a59https://doi.org/10.1016/j.arabjc.2017.12.008
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