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April 27, 2005Journal of the American Chemical Society480 citations

Osmium Diboride, An Ultra-Incompressible, Hard Material

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RCRobert W. CumberlandMWMichelle B. WeinbergerJGJohn J. Gilman

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Abstract

The need for wear- and scratch-resistant materials drives the quest for new superhard materials. In this work, we apply two design parameters to identify ultra-incompressible, superhard materials-high valence electron density and high bond covalency. Our first example of such a material is OsB2. The bulk modulus of OsB2 was measured using in situ high-pressure X-ray diffraction and was determined to be in the range of 365-395 GPa. While this value is slightly less than that of the bulk modulus of diamond, due to the anisotropic crystal structure of OsB2, the axis compressibility in the orthorhombic c-direction is less than the axis compressibility found in diamond. OsB2 also scratches the surface of a sapphire window, indicating that the hardness of OsB2 exceeds 2000 kg/mm2.

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Cite This Study

Cumberland et al. (2005) studied this question.

synapsesocial.com/papers/69d7cc78a2a48916bbbedaachttps://doi.org/10.1021/ja043806y
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