PulseExploreJournal ClubDebatesTrendingResearchersJournals
Instagram
HomeExploreJournal ClubTrending
Synapse
⌘+K
Synapse
November 17, 2015The Journal of Physical Chemistry Letters236 citationsOpen Access

Are Mobilities in Hybrid Organic–Inorganic Halide Perovskites Actually “High”?

TBThomas M. BrennerDEDavid A. EggerARAndrew M. Rappe

Key Points

  • Assess whether electronic carrier mobilities in hybrid organic–inorganic halide perovskites are truly high and identify the electron-lattice coupling mechanisms governing room-temperature transport.
  • Reviewed experimental and theoretical literature evaluating charge carrier mobilities in hybrid organic–inorganic perovskites relative to traditional high-efficiency inorganic semiconductors.
  • Analyzed room-temperature electron-lattice coupling and scattering mechanisms, focusing on acoustic phonon interactions and polaron dynamics.
  • Established that electronic carrier mobilities in typical hybrid organic–inorganic perovskites are relatively low compared to conventional inorganic semiconductors used in high-efficiency photovoltaics.
  • Identified acoustic phonon scattering and polaron formation as probable causes for carrier scattering while noting unresolved theoretical and experimental discrepancies in existing models.

Abstract

We present an experimental and theoretical viewpoint on the electronic carrier mobilities of typical hybrid organic-inorganic perovskites (HOIPs). While these mobilities are often quoted as high, a review of them shows that although otherwise the semiconducting properties of HOIPs are impressively good, mobilities of HOIPs used in most solar cells are actually not that high. This is especially apparent if they are compared to those of inorganic semiconductors used in other high efficiency solar cells. We critically examine possible causes and focus on electron-lattice coupling mechanisms that are active at room temperature, and can lead to carrier scattering. From this, we propose scattering due to acoustic phonons or polarons as possible causes, but also point out the difficulties with each of these in view of additional experimental and theoretical findings in the literature. Further research in this direction will contribute to making HOIP solar cells even more efficient than they already are.

Ask AI
Helpful
Bookmark
Share
View Full Paper

Cite This Study

Brenner et al. (2015) studied this question.

synapsesocial.com/papers/69d7f94205ee2ba81dbeeb30https://doi.org/10.1021/acs.jpclett.5b02390
Ask AI
Helpful
Bookmark
Share
View Full Paper