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April 26, 2000Organic Letters126 citations

Imposing Curvature on a Polyarene by Intramolecular Palladium-Catalyzed Arylation Reactions:  A Simple Synthesis of Dibenzoa,gcorannulene

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HRHelge A. ReischMBMatthew S. BratcherLSLawrence T. Scott

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Abstract

Palladium catalysis has been found to offer an effective solution-phase alternative to gas-phase flash vacuum pyrolysis as a method for converting the planar ring system of 7, 10-di(2-bromophenyl)fluoranthene (4) to that of the C(28)H(14) bowl-shaped fullerene fragment dibenzoa,gcorannulene (5).

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Cite This Study

Reisch et al. (2000) studied this question.

synapsesocial.com/papers/69d894eb3820cb9694d17c83https://doi.org/10.1021/ol005755p
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