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April 12, 2026Chemical Communications

Copper-mediated photoinduced perfluoroalkylation of arylsulfonium salts

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Authors

YYYun YangLZLili ZhaoSLShengsheng Luo

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Overview

Copper-mediated cross-coupling achieves site-selective perfluoroalkylation in aryl thianthrenium salts, suggesting a versatile new method.

Key Points

  • The research aims to develop a new method for site-selective perfluoroalkylation of arenes using copper and visible light.
  • Utilized copper-mediated cross-coupling
  • Incorporated aryl thianthrenium salts with [(DMPU)2Zn(Rf)2] reagents
  • Demonstrated through various substrates and functional groups
  • Applied visible light to promote the reaction
  • Successfully achieved a broad substrate scope for perfluoroalkylation
  • Showed outstanding tolerance for various functional groups
  • Created chain-length-tunable perfluoroalkylated compounds with diverse applications

Cite This Study

Yang et al. (2026) studied this question.

synapsesocial.com/papers/69db36e64fe01fead37c4dc7https://doi.org/10.1039/d6cc01493c
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