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January 1, 2022Energy & Environmental Science242 citations

Electrolyte design implications of ion-pairing in low-temperature Li metal batteries

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JHJohn HoloubekKKKangwoon KimYYYijie Yin

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Abstract

The reversibility of Li metal batteries suffers beneath 0 °C due to a heightened charge-transfer barrier. Herein, the introduction of ion-pairs within the electrolyte is shown to improve this behavior, enabling hundreds of cycles down to −40 °C.

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Holoubek et al. (2022) studied this question.

synapsesocial.com/papers/69dbcba0498b35d3e6a3d28bhttps://doi.org/10.1039/d1ee03422g
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