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December 15, 1980The Journal of Chemical Physics1,584 citations

Sideband intensities in NMR spectra of samples spinning at the magic angle

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JHJudith HerzfeldABAlan E. Berger

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Abstract

General integral and series expressions are derived for the intensities of sidebands observed in the magic angle spectra of inhomogeneously broadened I=1/2 systems. The expressions are evaluated for a wide range of shift parameters and the results used to construct graphical and numerical methods for extracting the principal values of chemical shift tensors from the intensities of just a few sidebands. The methods are illustrated by application to 31P spectra of barium diethyl phosphate. The results agree well with previous single crystal measurements.

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Cite This Study

Herzfeld et al. (1980) studied this question.

synapsesocial.com/papers/69dbd920498b35d3e6a3d435https://doi.org/10.1063/1.440136
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