PulseExploreJournal ClubDebatesTrendingResearchersJournals
Instagram
HomeExploreJournal ClubTrending
Synapse
⌘+K
Synapse
February 8, 2012Angewandte Chemie International Edition289 citations

From Esters to Alcohols and Back with Ruthenium and Osmium Catalysts

View Full Paper
DSDenis M. SpasyukSSSamantha A. M. SmithDGDmitry G. Gusev

Key Points

Key points are not available for this paper at this time.

Abstract

There and back again: hydrogenation of esters and the reverse reaction of dehydrogenative coupling of alcohols are efficiently catalyzed by dimeric complexes of Ru and Os under neutral conditions. The Os dimer is an outstanding catalyst for the hydrogenation of alkenoates and triglycerides, and allows production of fatty alcohols from olive oil. This complex converts ethanol into ethyl acetate and hydrogen under reflux.

Ask AI
Helpful
Bookmark
Share
View Full Paper

Cite This Study

Spasyuk et al. (2012) studied this question.

synapsesocial.com/papers/69dcb3b2f3d3790cb713384bhttps://doi.org/10.1002/anie.201108956
Ask AI
Helpful
Bookmark
Share
View Full Paper