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Distinctive from their 1D and 0D counterparts, 2D nanomaterials (2DNs) exhibit surface corrugations (wrinkles and ripples) and crumples. Thermal vibrations, edge instabilities, thermodynamically (interatomic) interactions, strain in 2D crystals, thermal contraction, dislocations, solvent, pre-strained substrate-relaxation, surface anchorage and high solvent surface tension during cause wrinkles or ripples to form on graphene. These corrugations on graphene can modify its structure, create polarized carrier puddles, induce pseudomagnetic field in bilayers and alter properties. This review outlines the different mechanisms of wrinkle, ripple and crumple, and the interplay between wrinkles’ and ripples’ attributes (wavelength/width, amplitude/, length/size, and bending radius) and graphene’s electronic properties and other mechanical, , surface, and chemical properties. Also included are brief discussions on corrugation-induced wettability and transmittance in graphene, modulation of its chemical potential, enhanced storage and strain sensing via relaxation of corrugations. Finally, the review summarizes the areas of research for 2D corrugations and crumples.
Deng et al. (2015) studied this question.