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January 1, 1993Journal of the Chemical Society Chemical Communications53 citations

Silicone grease as a precursor to a pseudo crown ether ligand: crystal structure of K+3K(Me2SiO)7+InH(CH2CMe3)3–4

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MCMelvyn Rowen ChurchillCLCharles H. LakeSCSun-Hua L. Chao

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Abstract

The crystallization of KInH(CH2CMe3)3 from heptane in the presence of silicone grease led to the formation of the title compound, in which one potassium cation is surrounded by a planar cyclo-(Me2SiO)7 ligand; K+⋯ O distances range from 2.86(3) to 2.99(4)Å.

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Cite This Study

Churchill et al. (1993) studied this question.

synapsesocial.com/papers/69df3eb044b0122c4f7a0ff5https://doi.org/10.1039/c39930001577
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